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Blank and Prinz, 2014

Following the rate determining formation of 8-enolate , this intermediate shows only marginal stabilization over the corresponding transition state and evolves to 8-B4 in a barrierless step

Metabololipidomics For oxylipin analysis, 200 L culture supernatants were transferred to 2 mL of ice-cold methanol containing 10 L of deuterium-labeled internal standards (200 nM d8-5S-HETE, d4-LTB 4 , d5-LXA 4 , d5-RvD 2 , d4-PGE 2 and 10 M d8-AA