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The solid according to claim 1, wherein the ligand L is a di-, tri- or tetracarboxylate ligand selected from the group consisting of: C 2 H 2 (CO 2 " ) 2 (fumarate), C 2 H 4 ( CO 2 " ) 2 (succinate), C 3 H 6 (CO 2 " ) 2 (glutarate), C 4 H 4 (CO 2 " ) 2 (muconate), C 4 H 8 (CO 2 " ) 2 (adipate) , C 7 H 14 (CO 2 " ) 2 (azelate), C 5 H 3 S (CO 2 " ) 2 (2,5-thiophene dicarboxylate), C 6 H 4 (CO 2 " ) 2 (terephthalate), C 6 H 2 N 2 (CCV) 2 (2,5-pyrazine dicarboxylate), C 10 H 6 (CO 2 " ) 2 (naphthalene-2,6-dicarboxylate), C 12 H 8 (CO 2 " ) 2 ( biphenyl-4,4'-dicarboxylate), C 12 H 8 N 2 (CO 2 " ) 2 6 H 3 ( CO 2 " ) 3 (benzne-1,2 ,4- tricarboxylate) , C 6 H 3 ( CO 2 " ) 3 ( benzne-1, 3,5- tricarboxylate) , C 24 H 15 ( CO 2 " ) 3 ( benzne-1, 3,5- tribenzoate) , C 6 H 2 ( CO 2 " ) 4 (benzne-1,2,4,5- ttracarboxylate, C 10 H 4 ( CO 2 " ) 4 ( naphtalne-2 , 3 , 6,7- ttracarboxylate) , C 10 H 4 (CO 2 " ) 4 (naphtalne-1, 4,5,8- ttracarboxylate), C 12 H 6 ( CO 2 " ) 4 (biphnyl-3,5,3 ' ,5' - ttracarboxylate) , et les analogues modifis choisis dans le groupe comprenant le 2-aminotrphtalate, le 2- nitrotrphtalate, le 2-mthyltrphtalate, le 2- chlorotrphtalate, le 2-bromotrphtalate, le 2,5- dihydroxotrphtalate , le ttrafluorotrphtalate, le le ttramthyltrphtalate, le dimthyl-4,4 ' - biphnydicarboxylate , le ttramthyl-4 , 4 ' - biphnydicarboxylate , le dicarboxy-4 , 4 ' - biphnydicarboxylate , le 2,5-pyrazyne dicarboxylate, le 2,5 diperfluoroterephthalate, azobenzene 4,4'- dicarboxylate, 3,3 ' -dichloro azobenzene 4,4'- dicarboxylate, 3 , 3 ' -dihydroxo azobenzene 4,4'- dicarboxylate, 3,3 '-diperfluoro azobenzene 4,4'- dicarboxylate, 3,5,3 ' ,5 '-azobenzene ttracarboxylate, 2,5-dimethyl terephthalate, perfluorosuccinate, perfluoromuconate, perfluoro glutarate, 3, 5, 3 ',5' perfluoro-4 , 4 ' -azobenzene dicarboxylate , 3,3'- diperfluoro azobenzene 4,4 '-dicarboxylate.(azobenzenedicarboxylate), C 6 H 3 (CO 2 - ) 3 (benzene-1,2,4-tricarboxylate), C 6 H 3 (CO 2 - ) 3 (benzene-1,3,5-tricarboxylate), C 24 H 15 (CO 2 " ) 3 (benzene-1,3,5-tribenzoate), C 6 H 2 (CO 2 " ) 4 (benzene-1,2,4,5-tetracarboxylate, C 10 H 4 (CO 2 ") 4 (naphthalene-2, 3, 6,7-tetracarboxylate), C 10 H 4 (CO 2") 4 (naphthalene-1, 4,5,8- tetracarboxylate), C 12 H 6 (CO 2 ") 4 (biphenyl-3,5,3 ', 5'-tetracarboxylate), and modified analogs selected from the group consisting of 2-aminoterephthalate, 2-nitroterephthalate, 2-methylterephthalate, 2-chloroterephthalate, 2-bromoterephthalate , 2,5-dihydroxterephthalate, tetrafluoroterephthalate, tetramethylterephthalate, dimethyl-4,4'-biphenydicarboxylate, tetramethyl-4,4'-biphenydicarboxylate, dicarboxy-4,4'-biphenydicarboxylate, 2,5-dihydroxterephthalate, pyrazyne dicarboxylate, 2,5 diperfluoroterephthalate, azobenzene 4,4'-dicarboxylate, 3,3 dichloroazobenzene 4,4'-dicarboxylate, 3,3'-dihydroxoazobenzene 4,4'-dicarboxylate, 3,3'-diperfluoroazobenzene 4,4'-dicarboxylate, 3,5,3 ', 5'-azobenzene tetracarboxylate, 2,5-dimethyl terephthalate, perfluorosuccinate, perfluoromuconate, perfluoro glutarate, 3,5 ', 3', 5 'perfluoro-4,4'-azobenzene dicarboxylate, 3,3'-diperfluoro azobenzene 4,4'-dicarboxylate
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